Physical chemistry of adsorption and catalysis

Like literature, philosophy is not distinguished from other subjects by a specific approach to a subject-matter independent of it. Chemistry deals with chemicals, biology with life and astronomy with very large, very distant objects. Philosophy can boast no such definite subject-matter.

Every chemical substance, whether natural or artificial, falls into one of two major categories, according to the spatial characteristic of its form. The distinction is between those substances that have a plane of symmetry and those that do not. The former belong to the mineral, the latter to the living world.

Due to economic and ecological factors, catalytic processes in the pro duction of fine chemicals are gaining in importance, especially in the area of asymmetric catalysis (Collins et al. 1997; Breuer et al. 2004). Accordingly, the practicing chemist has three major options: transition metal catalysts (Jacobsen et al. 1999), organocatalysts (Berkessel and Gröger 2004) or enzymes (Drauz and Waldmann 2002; Liese et al. 2006). All of them have advantages and disadvantages, which means that a given type of catalysis cannot be expected to provide general so lutions to all problems of relevance in academic and industrial labora tories. Therefore, research in all three approaches needs to be intensified.